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#1 2024-09-30 19:34:01

tahanson43206
Moderator
Registered: 2018-04-27
Posts: 18,915

Fluidized Sand Thermal Energy Storage

For SpaceNut .... we did not seem to have a topic that captures this announcement by an Italian company....

https://www.yahoo.com/tech/storage-solu … 29555.html

thermal technology: 'Critical to reach net-zero'
Innovators from Italy's Magaldi Green Thermal Energy Storage plan to fight planet warming with an unlikely ally: heat.

It's part of a unique method to store intermittent renewable energy using fluidized sand. Fascinatingly, the system has the crucial steps familiar to batteries — charging, storing, and discharging — without the expensive metals needed for power-pack chemistry to work.

The sand collects heat generated from surplus renewable energy, with a heat exchanger to manage the process. A well-insulated tank keeps the sand packs inside hot with little energy loss.

To discharge, the heat exchanger reverses, releasing superheated steam at up to 752 degrees Fahrenheit. The hot air can make electricity by powering a turbine, according to Magaldi and Renewable Energy Magazine.

"Our storage technology can be used in the steam section of existing thermoelectric power plants … or combined cycle gas turbine plants," Letizia Magaldi, Magaldi's executive vice president, said in a 2021 PV Magazine article on the patented tech.

Heat generation is an energy

This forum contains a number of suggestions for storing thermal energy using a great variety of materials.


I'm hoping a member (or two perhaps) will compare this method to others in the archive.


(th)

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#2 2024-09-30 19:34:58

tahanson43206
Moderator
Registered: 2018-04-27
Posts: 18,915

Re: Fluidized Sand Thermal Energy Storage

This post is reserved for an index to posts that may be contributed by NewMars members over time.

(th)

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#3 2024-09-30 19:50:14

tahanson43206
Moderator
Registered: 2018-04-27
Posts: 18,915

Re: Fluidized Sand Thermal Energy Storage

in opening this topic, I had no idea what "fluidized Sand" might be .... Google came up with a couple of snippets...

Search Labs | AI Overview
Learn more

Fluidized sand is a phenomenon that occurs when a solid, like sand, behaves like a liquid when pressurized air is forced through it. This happens because the air pressure balances out the weight of the sand grains, making them less dense and easier to move around.
Fluidized sand has many uses, including:
Fluidized sand beds
These beds can be used to demonstrate how sand can act like a liquid, and how objects can sink and float in it.
Fluidized sand baths
These baths use a fluidized mass of fine particles, like aluminum oxide, to distribute heat evenly. They are a safer, cleaner, and more cost-effective alternative to other types of baths.
Fluidized sand heating beds
These beds use sand to gently clean industrial metal components, grease, and grime. They are efficient, safe, and environmentally friendly.
Fluidized bed powder coating
This process uses a fluidized bed to suspend finely ground powder particles in air. A preheated part is dipped into the powder bath, and the melted particles fuse to the object.
Liquidized Sand Machine - YouTube
application was created in 1922 to burn coal more efficiently the process combines a pressurized fluid a liquid or a g...


Nick Uhas  · 
YouTube · 6y
Design and management of conventional fluidized-sand biofilters - ScienceDirect

ScienceDirect.com
Fluidized Sand Heating Bed Work - What is it? - Schaus-Vorhies, Co.
Dec 9, 2020

Schaus-Vorhies Companies
Show all
Show more
A fluidized sand bath consists of a loosely packed mass of fine solid particles (aluminium oxide ) through which an upward flow of air is passed. In the fluidized state, the aluminium oxide particles become mobile, and the bath displays many of the properties of a liquid.Jun 27, 2023

Fluidized Sand Bath Selection Guide - Cole-Parmer

(th)

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#4 2024-10-01 07:14:16

Calliban
Member
From: Northern England, UK
Registered: 2019-08-18
Posts: 3,717

Re: Fluidized Sand Thermal Energy Storage

This idea would certainly work.  It has the advantage of a high technological readiness, given that steam plants, resistance heaters and thermal storage in sand are all well understood technologies.  This is an idea that could be developed into a practical solution quickly.  In fact, this is probably the easiest grid electricity storage solution to develop quickly and at scale.

The problem with it is that the steam powerplant has to buy already generated electricity off the grid, turn it into heat, store it and then reconvert the heat into electricity.  At 752 farenheit (~400°C), a large steam plant could realistically convert about one third of the heat into electricity, with the rest being low grade waste heat that we may or may not have a use for.  Ignoring all other costs, the plant will need to sell electricity for three times the price they buy it for just to break even.  Including capital, operating, maintenance costs and profit, the price will need to be several times higher.  Not necessarily an unworkable idea, but it clearly faces obstacles.

It would work a bit better from an efficiency standpoint if it could be integrated into a town district heating system.  Such a plant could avoid the construction of cooling towers, which would marginally reduce construction costs.  The problem is that waste heat is worth a lot less than electricity.  So the plant wouldn't get much compensation for selling the heat.  To a certain extent, we may need to accept this as a fact of life.  To turn intermittent electricity into dependable electricity is going to cost money and require capital equipment.  There is no solution on the cards that avoids that reality.  One other advantage that a steam plant offers that may cushion its cost impact, is long system life.  With good water chemistry control, a steam plant can live for 80 years, perhaps longer.  So it is in many ways a gift to future generations.  After 30 years of operation, capital costs are mostly gone.  But a well cared for plant could operate for another fifty.

Last edited by Calliban (2024-10-01 07:18:43)


"Plan and prepare for every possibility, and you will never act. It is nobler to have courage as we stumble into half the things we fear than to analyse every possible obstacle and begin nothing. Great things are achieved by embracing great dangers."

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#5 2024-10-03 18:54:23

SpaceNut
Administrator
From: New Hampshire
Registered: 2004-07-22
Posts: 29,425

Re: Fluidized Sand Thermal Energy Storage

We have talked about sand but adding liquid now creates internal tank storage pressure. Sand battery was discussed in the Geothermal and Geothermal Battery (Changed Title 12/21/23) a Void started topic.

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#6 2024-10-04 17:26:16

SpaceNut
Administrator
From: New Hampshire
Registered: 2004-07-22
Posts: 29,425

Re: Fluidized Sand Thermal Energy Storage

An image to go with words

afbd98359b74b360ede6abab22fb1c7b

heat exchanger imbedded in the sand

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#7 Yesterday 18:02:31

SpaceNut
Administrator
From: New Hampshire
Registered: 2004-07-22
Posts: 29,425

Re: Fluidized Sand Thermal Energy Storage

I take the word sand as sand being crushed grains that are fine from earth soils and rock. The pipes extend in through the sand and come out the other side. The heat is coming from exhaust heat or from heated air or any other working fliud, or gas that is pumped through the system.

Magaldi's website states that its thermal unit is sustainable, made with silica sand and steel.

charging, storing, and discharging

To discharge, the heat exchanger reverses, releasing superheated steam at up to 752 degrees Fahrenheit.

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#8 Yesterday 18:44:56

tahanson43206
Moderator
Registered: 2018-04-27
Posts: 18,915

Re: Fluidized Sand Thermal Energy Storage

For SpaceNut .... we (in NewMars) are never going to get anywhere if we keep thinking new announcements are the same as previous ones.

The only thing I ** know ** is different about this concept is that air is used to move the sand particles.

The advantage would appear to be increased thermal storage capability.

You've shown us old fashioned sand storage, in which the sand does not move.

If you can (somehow) find a bit of time to investigate, please see if the Italians have improved upon the ancient sand pile concept you showed us in Post #6.

Let's see if we can accomplish something useful with this topic.

(th)

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#9 Yesterday 19:39:54

kbd512
Administrator
Registered: 2015-01-02
Posts: 7,771

Re: Fluidized Sand Thermal Energy Storage

SpaceNut,

If you've ever been to the Middle East, they have lots of sand there, but it's nothing like the "beach sand" I think of as a child from swimming in the Gulf of Mexico or in the Pacific near San Diego.  It's as fine as talcum powder.  It's every bit as hard and abrasive, but much finer, with a consistency closer to flour than what I think of as "beach sand".

If you put that flour-like consistency sand into a highly pressurized container with say, CO2, then I would assume if you tried to stir-up the sand that you could more uniformly inject or extract thermal energy.  This "stirring action" doesn't need to be performed using a mechanical device.  It could be performed by pumping or circulating CO2 from the bottom to the top of the container.  Thus, you have "fluidized" sand that is constantly churning about inside the container, either soaking up or releasing heat.

If you were intent on extracting stored heat, then because sand is also a reasonably good insulator, the sand surrounding the heat transfer pipe becomes cooler, so the sand further away from the heat transfer pipe (which is most of it) cannot efficiently re-radiate heat to uniformly draw-down the temperature as heat is extracted.  If the sand was fluidized, then you're able to continuously stir up the sand, so any temperature decrease or increase is more uniformly distributed across all of the sand inside the pressure vessel.  This means you can have a simplistic stationary "heat pipe" inside the container for thermal power transfer, because the gas is constantly mixing up the sand is keeping your temperature uniform.  You don't create "hot spots" or "cold spots" near the heat pipe.

I haven't read anything about what they're doing here, but just looking at that photo you posted, that's what it looks like to me.  I would guess that you could also use water or oil or wax or molten salt for thermal power transfer, but CO2 would allow for the highest temperatures.  Molten salt is the only high temperature heat exchange medium which would operate at atmospheric pressure, unless temperatures are kept relatively low, in which case oil or wax would also operate without pressure.

Sand can store about 290J/kg°C, so it needs to go to high temperatures to be mass and volume efficient.

Desert sand can be thermally stable between 650°C and 1000°C. However, the first heating cycle can cause the sand to lose mass and transform calcium carbonate into calcium oxide, which can negatively impact its solar absorption.

Foundry sand has a low volatile content and its main components are stable at high temperatures. It doesn't readily evaporate.

Sand has a melting point of roughly 1,700°C (3,090°F). It's also chemically stable and has no vapor pressure.

Sand can also be used as a thermal energy storage (TES) material. For example, Hitec®-saturated sand can be used to store and extract more energy than concrete at thermal storage temperatures ranging from 400°C and 500°C.

Water, oil, and paraffin wax are not going to survive 400°C, never mind higher temperatures.  CO2 molecules begin to thermally dissociate around 1,727°C.  Steel melts around 1,370°C.  Concrete will melt near 1,150°C.  Alumina / Aluminum oxide refractory ceramic vessels will melt around 2,072°C.  Sand is about 1,500kg/m^3, so 1.5X denser than water, but even across a 1,000°C temperature delta, sand can only store 290kJ/kg or 435,000,000J/m^3 or 120,833Wh/m^3.  If you're about 50% efficient at extracting the heat energy, then your actual storage density is half of that.

According to rough estimations, the Earth is estimated to have around 2.5 x 10^15 cubic meters of sand

That's 2,500,000km^3 of sand on the Earth's surface, thus there is no shortage, nor is there ever likely to be a shortage.  We would need about 19.726km^3 of sand to store energy for 90 days, to account for our seasonal energy demand.  That's quite a lot of sand, but such a system would be remarkably stable over a very long period of time.  As long as you don't subject the ceramic storage containers to thermal shocks or impact loads, it's almost immortal.

However, you could store a lot more energy at much lower temperatures

Al2O3: 880J/kg⋅°C * (800°C - 200°C) = 528,000J/kg
Fe2O3: 750J/kg⋅°C * (800°C - 200°C) = 450,000J/kg

Al2O3 is stable in air, up to 1,650°C.
Al2O3: 880J/kg⋅°C * (1,500°C - 500°C) = 880,000J/kg

Al2O3 is 3,890kg/m^3, so it would require far less volume, at 3,423,200,000J/m^3 or 950,889Wh/m^3.  It has 7.87X greater thermal storage capacity than sand over the same temperature range.  Aluminum oxide is almost 7% of the weight of the Earth's crust, so no shortage of that stuff, either.  Turning it into Aluminum metal requires a crazy amount of energy, but Alumina is much easier to obtain from far less energy input.

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#10 Today 06:16:27

tahanson43206
Moderator
Registered: 2018-04-27
Posts: 18,915

Re: Fluidized Sand Thermal Energy Storage

For SpaceNut ... taking the post #9 as a guide, and if you have the time and this topic is of interest, please compare what the Italians are doing to the system you showed us, which does NOT use the "fluidizing" process.

My guess is that the fluidizing process is ONLY needed when the operator is adding or withdrawing thermal energy from the store.

After all, it is going to take energy to fluidize the store, so you'd only use it when you are adding energy or withdrawing it.

Otherwise, the store would sit quietly at whatever temperature it was given, for extended periods due to the poor thermal conductivity of the unfluidized material.

It would be ** really ** interesting to see actual numbers for the new process compared to the traditional one.

(th)

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